Formulas for IPhO
Based on the IPhO formula sheet by Jaan Kalda (v. July 4, 2018). Use the search bar to find any formula instantly.
I. Mathematics
1. Taylor Series
Linear approximation: \(F(x) \approx F(x_0) + F'(x_0)(x - x_0)\). For \(|x| \ll 1\): \(\sin x \approx x\), \(\cos x \approx 1 - x^2/2\), \(e^x \approx 1 + x\), \(\ln(1+x) \approx x\), \((1+x)^n \approx 1 + nx\).
2. Perturbation Method
Find the solution iteratively using the solution to the "non-perturbed" (directly solvable) problem as the 0th approximation; corrections for the next approximation are calculated on the basis of the previous one.
3. Linear Differential Equation with Constant Coefficients
\(\lambda_{1,2}\) are solutions of the characteristic equation \(a\lambda^2 + b\lambda + c = 0\) (if \(\lambda_1 \neq \lambda_2\)). If the solution is complex with \(\lambda_{1,2} = \gamma \pm i\omega\), then \(y = Ce^{\gamma x}\sin(\omega x + \varphi_0)\).
4. Complex Numbers
\(\bar{z} = a - ib = |z|e^{-i\varphi}\), \(|z|^2 = z\bar{z} = a^2 + b^2\), \(\varphi = \arg z = \arcsin\frac{b}{|z|}\). \(\text{Re}\,z = (z+\bar{z})/2\), \(\text{Im}\,z = (z-\bar{z})/2\). \(|z_1 z_2| = |z_1||z_2|\), \(\arg z_1 z_2 = \arg z_1 + \arg z_2\). Euler's formula: \(e^{i\varphi} = \cos\varphi + i\sin\varphi\). \(\cos\varphi = \frac{e^{i\varphi}+e^{-i\varphi}}{2}\), \(\sin\varphi = \frac{e^{i\varphi}-e^{-i\varphi}}{2i}\).
5. Cross and Dot Products
\(\vec{a}\times\vec{b} = -\vec{b}\times\vec{a} \perp \vec{a},\vec{b}\). Components: \(\vec{a}\times\vec{b} = (a_y b_z - b_y a_z)\vec{e}_x + (a_z b_x - b_z a_x)\vec{e}_y + \cdots\). BAC-CAB rule: \(\vec{a}\times[\vec{b}\times\vec{c}] = \vec{b}(\vec{a}\cdot\vec{c}) - \vec{c}(\vec{a}\cdot\vec{b})\). Mixed product (volume of parallelepiped): \((\vec{a},\vec{b},\vec{c}) \equiv \vec{a}\cdot[\vec{b}\times\vec{c}] = [\vec{a}\times\vec{b}]\cdot\vec{c}\).
6. Cosine and Sine Laws
\(R\) — the circumradius of the triangle.
7. Trigonometric Identities
\(\tan(\alpha\pm\beta) = \frac{\tan\alpha + \tan\beta}{1 \mp \tan\alpha\tan\beta}\). Double angle: \(\cos^2\alpha = \frac{1+\cos 2\alpha}{2}\), \(\sin^2\alpha = \frac{1-\cos 2\alpha}{2}\). Product-to-sum: \(\cos\alpha\cos\beta = \frac{\cos(\alpha+\beta)+\cos(\alpha-\beta)}{2}\). Sum-to-product: \(\cos\alpha + \cos\beta = 2\cos\frac{\alpha+\beta}{2}\cos\frac{\alpha-\beta}{2}\).
8. Inscribed Angle Theorem
An angle inscribed in a circle is half of the central angle that subtends the same arc. Corollaries: the hypotenuse of a right triangle is the diameter of its circumcircle; if opposite angles of a quadrilateral are supplementary, it is a cyclic quadrilateral.
9. Triangle Area
\(h_a\) — altitude to side \(a\), \(p\) — semi-perimeter, \(r\) — inradius, \(R\) — circumradius.
10. Triangle Centroid
The centroid is the intersection point of the medians and divides each median in the ratio 2:1 from vertex to midpoint.
12. Derivatives
\((\sin x)' = \cos x\), \((\cos x)' = -\sin x\), \((e^x)' = e^x\), \((\ln x)' = 1/x\), \((x^n)' = nx^{n-1}\), \((\arctan x)' = 1/(1+x^2)\), \((\arcsin x)' = 1/\sqrt{1-x^2}\).
13. Integration
Integration formulas are the inverses of derivative formulas. Substitution method special case: \(\int f(ax+b)\,dx = F(ax+b)/a\).
14. Conic Sections
\(a_{11} = a_{22}\) — circle; \(a_{11}(a_{11}a_{22}-a_{12}^2) > 0\) — ellipse; \(< 0\) — hyperbola; \(a_{11}a_{22}=a_{12}^2\) — parabola. Ellipse: \(l_1 + l_2 = 2a\), \(\alpha_1 = \alpha_2\), \(A = \pi ab\). Hyperbola: \(l_1 - l_2 = 2a\). Parabola: \(l + h = \text{const}\), \(\alpha_1 = \alpha_2\).
15. Numerical Methods
Newton's iterative method for finding roots \(f(x) = 0\). Trapezoidal rule: \(\int_a^b f(x)\,dx \approx \frac{b-a}{2n}[f(x_0) + 2f(x_1) + \cdots + 2f(x_{n-1}) + f(x_n)]\).
16. Derivatives and Integrals of Vectors
Differentiate/integrate each component; alternatively differentiate by applying the triangle rule for the difference of two infinitesimally close vectors.
II. General Recommendations
1. Check Formulas for Veracity
a) Examine dimensions; b) test simple special cases (two parameters equal, one parameter tends to 0 or \(\infty\)); c) verify the plausibility of the solution's qualitative behaviour.
2. Extraordinary Coincidences
If there is an extraordinary coincidence in the problem text (e.g. two things are equal), then the key to the solution might be there.
4. Postpone Calculations
Postpone long and time-consuming mathematical calculations to the very end (when everything else is done) while writing down all the initial equations which need to be simplified.
5. Hopelessly Difficult Problems
If the problem seems to be hopelessly difficult, it has usually a very simple solution (and a simple answer). This is valid only for Olympiad problems, which are definitely solvable.
III. Kinematics
1. Translational Motion of a Point/Rigid Body
Also: \(t = \int v_x^{-1}\,dx = \int a_x^{-1}\,dv_x\), \(x = \int \frac{v_x}{a_x}\,dv_x\). If \(a = \text{const}\): \(x = v_0 t + at^2/2 = (v^2 - v_0^2)/2a\).
2. Rotational Motion
Analogous to translational motion. \(\vec{\tau}\) — tangential unit vector, \(\vec{n}\) — normal unit vector, \(R\) — radius of curvature.
4. Motion of a Rigid Body
\(\vec{v}_A, \vec{v}_B\) — velocities of points A and B; \(\alpha, \beta\) — angles formed by \(\vec{v}_A, \vec{v}_B\) with line AB. The instantaneous center of rotation can be found as the intersection point of perpendiculars to \(\vec{v}_A\) and \(\vec{v}_B\).
5. Non-Inertial Reference Frames
\(\vec{a}_{\text{Cor}} \perp \vec{v}_1, \vec{\omega}\); \(\vec{a}_{\text{Cor}} = 0\) if \(\vec{v}_1 = 0\). Subscript 0 — frame, 1 — relative to frame, 2 — absolute.
6. Ballistic Problem
Reachable region boundary. For an optimal ballistic trajectory, initial and final velocities are perpendicular.
7. Fastest Paths
For finding fastest paths, Fermat's and Huygens's principles can be used.
IV. Mechanics
1. 2D Equilibrium of a Rigid Body
2 equations for force, 1 for torque. Torque is often better since "boring" forces can be eliminated by a proper choice of origin. If forces are applied only to 2 points, the net force lines coincide; for 3 points, the 3 lines meet at a single point.
2. Combined Contact Force
Normal force and friction force can be combined into a single force, applied to the contact point under angle \(\arctan\mu\) with respect to the normal force.
3. Newton's 2nd Law (Translational and Rotational)
\(\vec{M} = \vec{r}\times\vec{F}\). For 2D geometry, \(M\) and \(\varepsilon\) are scalars and \(M = Fl = F_t r\), where \(l\) is the arm of a force.
4. Generalized Coordinates
Let the system's state be defined by a parameter \(\xi\) with potential energy \(\Pi = \Pi(\xi)\) and kinetic energy \(K = \frac{1}{2}\mu\dot\xi^2\). Hence for translational motion: force is the derivative of potential energy.
5. System of Mass Points
Moment of inertia about the z-axis: \(I_z = \sum m_i(x_i^2 + y_i^2) = \int(x^2 + y^2)\,dm\).
6. Center-of-Mass Frame
Index \(c\) denotes quantities relative to the mass center. \(\vec{P} = \vec{P}_c + M_\Sigma\vec{v}_c\).
7. Steiner's (Parallel Axis) Theorem
\(b\) — distance of the mass center from the rotation axis, \(I_c\) — moment of inertia about the axis through the mass center.
8. Newton's 2nd Law for Systems
With \(\vec{P}\) and \(\vec{L}\) from point 5.
11. Physical Pendulum
\(\tilde{l}\) — reduced length. \(\omega(l) = \omega(\tilde{l}-l) = \sqrt{g/\tilde{l}}\).
12. Moments of Inertia Coefficients
Cylinder: \(\alpha = 1/2\). Solid sphere: \(\alpha = 2/5\). Thin spherical shell: \(\alpha = 2/3\). Rod (about center): \(\alpha = 1/12\) (about endpoint: \(\alpha = 1/3\)). Square: \(\alpha = 1/6\).
13. Conservation Laws
Momentum conservation can hold only along one axis. Angular momentum (arms of external forces are 0) can be written relative to 2 or 3 points, then substitutes conservation of linear momentum.
14. Additional Forces in Non-Inertial Frames
Coriolis force is perpendicular to velocity and does no work.
16. Collision of Two Bodies
Conserved: a) net momentum, b) net angular momentum, c) angular momentum of one body w.r.t. impact point, d) total energy (elastic). If sliding stops during impact, final velocities of contact points have equal projections to the contact plane. If sliding doesn't stop, the momentum delivered forms angle \(\arctan\mu\) with the normal.
17. Instantaneous Center of Rotation
Every motion of a rigid body can be represented as a rotation around the instantaneous center of rotation \(C\). NB: distance of a body point \(P\) from \(C\) is not equal to the radius of curvature of the trajectory of \(P\).
18. Tension in a String
For a massive hanging string, tension's horizontal component is constant and vertical changes according to the string's mass underneath. Pressure force (per unit length) of a string on a smooth surface is \(N = T/R\). Analogy: surface tension pressure \(p = 2\sigma/R\).
19. Liquid Surface Shape
Liquid surface takes an equipotential shape (neglecting surface tension). In an incompressible liquid, \(p = p_0 - w\), where \(w\) is the volume density of potential energy.
20. Bernoulli's Law
For incompressible fluid. In a homogeneous gravitational field, \(\varphi = gh\). For a gas of specific heat \(c_p\): \(\frac{1}{2}v^2 + c_p T = \text{const}\).
21. Momentum Continuity
Valid along straight streamlines.
22. Adiabatic Invariant
If the relative change of the parameters of an oscillating system is small during one period, the area of the loop drawn on the phase plane (in \(p\text{-}x\) coordinates) is conserved with very high accuracy.
23. Stability
For studying stability use: a) principle of minimum potential energy, or b) principle of small virtual displacement.
24. Virial Theorem
For finite (bounded) movement; \(\langle\cdot\rangle\) denotes time averages.
25. Tsiolkovsky Rocket Equation
\(u\) — exhaust velocity, \(M\) — initial mass, \(m\) — final mass.
V. Oscillations and Waves
1. Damped Oscillator
\(\gamma\) — damping coefficient, \(\omega_0\) — natural frequency.
2. Coupled Oscillators
Equation of motion for a system of coupled oscillators.
3. Eigenmodes
A system of \(N\) coupled oscillators has \(N\) eigenmodes with eigenfrequencies \(\omega_i\). General solution is a superposition of all eigenmotions with \(2N\) integration constants \(X_i\) and \(\phi_i\).
4. Small Oscillations Near Equilibrium
For a system with generalized coordinate \(\xi\), kinetic energy \(K = \frac{1}{2}\mu\dot\xi^2\), and equilibrium at \(\xi = 0\): \(\Pi(\xi) \approx \frac{1}{2}\kappa\xi^2\).
5. Wave Phase and Velocities
\(k = 2\pi/\lambda\) — wave vector. The value at \((x,t)\) is \(a_0\cos\varphi = \text{Re}\,(a_0 e^{i\varphi})\). \(v_f\) — phase velocity, \(v_g\) — group velocity.
6. Standing Waves and Superposition
For linear waves (electromagnetic, small-amplitude sound and water waves), any pulse can be considered as a superposition of sinusoidal waves. A standing wave is the sum of two identical counter-propagating waves.
7. Speed of Sound in a Gas
\(\gamma\) — specific heat ratio, \(p\) — pressure, \(\rho\) — density, \(\bar{v}\) — RMS molecular speed.
8. Speed of Sound in Elastic Material
\(E\) — Young's modulus, \(\rho\) — density.
9. Speed of Waves in Shallow Water and Strings
\(h\) — water depth, \(T\) — string tension, \(\rho_{\text{lin}}\) — linear mass density.
10. Doppler Effect
\(\nu_0\) — emitted frequency, \(v_\parallel\) — observer velocity component along line of sight, \(u_\parallel\) — source velocity component, \(c_s\) — speed of sound.
11. Huygens' Principle
Wavefront can be constructed step by step, placing an imaginary wave source in every point of the previous wavefront. Results are curves separated by distance \(\Delta x = c_s\Delta t\). Waves travel perpendicular to the wavefront.
VI. Geometrical Optics. Photometry
1. Fermat's Principle
The wave's path from point A to point B is such that the wave travels the least time.
2. Snell's Law
\(n_1, n_2\) — refractive indices, \(\alpha_1, \alpha_2\) — angles of incidence and refraction, \(v_1, v_2\) — wave speeds.
3. Continuous Refraction
If the refraction index changes continuously, divide the media into layers of constant \(n\) and apply Snell's law. Light ray can travel along a layer of constant \(n\) if the total internal reflection requirement is marginally satisfied: \(n' = n/r\), where \(r\) is the curvature radius.
4. Conservation of Photon Momentum Components
If refraction index depends only on \(z\), the photon's transverse momentum components \(p_x, p_y\) and energy are conserved.
5. Thin Lens Equation
\(a\) — object distance, \(b\) — image distance, \(f\) — focal length, \(D\) — optical power. Pay attention to signs.
6. Newton's Lens Equation
\(x_1, x_2\) — distances of the image and the object from the focal planes.
8. Geometric Ray Constructions
a) Ray through the lens center does not refract; b) ray parallel to the optical axis passes through the focus; c) after refraction, initially parallel rays meet at the focal plane; d) image of a plane is a plane; these two planes meet at the plane of the lens.
9. Photometry
Luminous flux \(\Phi\) [lumen]: energy of light weighted by eye sensitivity. Luminous intensity \(I\) [candela]: flux per solid angle. Illuminance \(E\) [lux]: flux per unit area.
10. Gauss Theorem for Luminous Flux
The flux through a closed surface surrounding point sources of intensity \(I_i\) is \(\Phi = 4\pi\sum I_i\). For a single source at distance \(r\): \(E = I/r^2\).
VII. Wave Optics
1. Diffraction (Huygens' Principle)
If obstacles cut the wavefront into fragments, divide the wavefront into small pieces which serve as imaginary point-like light sources; the wave amplitude at the observation site is the sum over the contributions of these sources.
2. Two-Slit Interference
\(a\) — slit separation, \(d \ll a, \lambda\) — slit width is much smaller than separation and wavelength, \(k = 2\pi/\lambda\).
3. Single-Slit Diffraction
\(d\) — slit width. The central maximum is double-wide. \(I \propto \sin^2\!\left(k\frac{d}{2}\sin\varphi\right)/\varphi\).
4. Diffraction Grating
Main maxima same as two-slit case; width of main maxima same as single slit with \(d\) — net grating length. \(n\) — order number, \(N\) — number of slits.
5. Resolving Power of a Spectral Device
\(L\) — optical path difference between the shortest and longest beams.
6. Resolving Power of a Prism
\(a\) — base length of the prism, \(dn/d\lambda\) — dispersion of the prism material.
7. Angular Resolution (Rayleigh Criterion)
\(d\) — aperture diameter. For that angle, the center of one point falls onto the first diffraction minimum of the other point.
8. Bragg Diffraction
\(a\) — distance between neighbouring crystal planes, \(\alpha\) — glancing angle, \(k\) — order of reflection.
9. Reflection Phase Shift
Reflection from an optically denser dielectric medium introduces a phase shift of \(\pi\). For semi-transparent thin films: \(\varphi_\to + \varphi_\leftarrow = \pi\).
10. Fabry-Perot Interferometer
Two parallel semi-transparent mirrors with large reflectivity \(r\) (\(1-r \ll 1\)). \(a\) — mirror separation.
11. Coherent EM Waves and Intensity
Electric fields are added; vector diagram can be used with angle between vectors as the phase shift. Dispersion: \(n = n(\omega) = \sqrt{\varepsilon(\omega)}\). \(E, B\) — RMS values.
12. Malus' Law
\(\varphi\) — angle between the polarization planes. Valid for linearly polarized light.
13. Quarter-Wave Plate
\(\lambda/4\)-plate introduces a phase shift of \(\pi/2\) between linearly polarized components.
14. Brewster's Angle
Reflected and refracted rays are perpendicular. The reflected ray is completely polarized.
VIII. Circuits
1. Ohm's Law and Power
\(U\) — voltage, \(I\) — current, \(R\) — resistance, \(P\) — power.
2. Kirchhoff's Laws
First law: sum of currents at any node is zero. Second law: sum of voltage drops around any closed loop is zero.
3. Methods to Reduce Equations
Method of node potentials; method of loop currents; equivalent circuits (any 3-terminal network can be transformed between \(\Delta\) and \(Y\); 2-terminal with emf becomes \(r\) and \(\mathcal{E}\) in series).
4. Infinite Resistor Networks
Resistance of an infinite chain: use self-similarity. Resistance between neighbour nodes of an infinite grid: use the generalized method of electrical images.
5. AC Circuits
Apply DC rules (pts. 1-4) while substituting \(R\) with \(Z\). Phase angle: \(\varphi = \arg Z\). \(U_{\text{eff}} = |Z|I_{\text{eff}}\). Power: \(P = |U||I|\cos(\arg Z) = \sum I_i^2 R_i\).
6. Characteristic Times
Relaxation to stationary current distribution is exponential, \(\propto e^{-t/\tau}\).
7. Energy Conservation in Circuits
\(q\) — charge that has crossed a potential drop \(U\). Work of emf is \(A = \mathcal{E}q\).
8. Stored Energy
\(C\) — capacitance, \(U\) — voltage, \(L\) — inductance, \(I\) — current.
9. Faraday's Law of Induction
\(\Phi\) — magnetic flux, \(B\) — magnetic field, \(S\) — area, \(L\) — inductance.
10. Nonlinear Elements
Graphical method: find the solution in \(U\text{-}I\) coordinates as an intersection point of a nonlinear curve and a line representing Ohm/Kirchhoff laws. In case of many intersection points, study stability.
11. Short- and Long-Time Limits
For \(t_{\text{obs}} \gg \tau\), quasiequilibrium is reached: \(I_C \approx 0\) (wire "broken" near \(C\)) and \(\mathcal{E}_L \approx 0\) (\(L\) effectively short-circuited). For \(t_{\text{obs}} \ll \tau\): \(C\) is "short-circuited" and \(L\) is "broken".
12. Current Continuity Through an Inductor
If \(L \neq 0\), then \(I(t)\) is a continuous function.
13. Superconducting Contour
Through a superconducting contour, magnetic flux \(\Phi = \text{const}\). With no external \(B\): \(LI = \text{const}\).
14. Mutual Inductance
\(I_2\) — current in a second contour. \(M\) — mutual inductance.
IX. Electromagnetism
1. Coulomb's Law
\(k = 1/(4\pi\varepsilon_0)\). Kepler's laws are applicable for \(1/r^2\) force.
2. Gauss's Law
\(Q\) — enclosed charge, \(M\) — enclosed mass.
3. Circulation Theorems
Line integrals around closed loops. The first equation becomes \(-\dot\Phi\) for time-varying magnetic flux (Faraday's law).
4. Biot-Savart Law
At the center of a circular current: \(B = \frac{\mu_0 I}{2r}\).
5. Lorentz Force
\(e\) — charge, \(\vec{v}\) — velocity, \(I\) — current, \(\vec{l}\) — wire length vector.
6. Fields from Gauss's and Circulation Laws
Inside a uniformly charged sphere/cylinder/layer of homogeneous \(\rho\) or \(\vec{j}\): \(\vec{E} = \frac{\rho}{d\varepsilon_0}\vec{r}\), \(\vec{B} = \frac{1}{d}\mu_0\vec{j}\times\vec{r}\), where \(d = 3\) (ball), \(d = 2\) (cylinder), \(d = 1\) (layer).
7. Solenoid
Outside a long solenoid: \(B = 0\). Flux: \(\Phi = NBS\), inductance: \(L = \Phi/I\). Short solenoid: \(B_\parallel = \frac{In\mu\mu_0\Omega}{4\pi}\) (\(\Omega\) — solid angle).
9. Potential Energy of Charges
\(\varphi(\vec{r})\) — potential at position \(\vec{r}\), \(dq = \rho(\vec{r})\,dV\).
13. Conductor Shielding
A conductor shields charges and electric fields. Charge distribution inside a hollow sphere cannot be seen from outside (it appears as a conducting ball carrying total charge \(Q\)).
14. Capacitances
\(S\) — plate area, \(d\) — plate separation, \(r\) — sphere radius, \(R, r\) — outer/inner radii of coaxial cable, \(l\) — cable length.
15. Dipole Moment
\(\vec{d}_e\) — electric dipole moment, \(\vec{d}_\mu\) — magnetic dipole moment, \(\vec{l}\) — separation vector, \(I\) — current, \(\vec{S}\) — loop area vector.
16. Energy and Torque of a Dipole
Energy and torque of a dipole in an external field.
17. Dipole Field
Potential and field of a dipole fall off as \(1/r^2\) and \(1/r^3\) respectively.
18. Force on a Dipole
Force is proportional to the field gradient. Interaction between two dipoles: \(F \propto r^{-4}\).
20. Method of Images
Grounded (superconducting for magnets) planes act as mirrors. Field of a grounded (or isolated) sphere can be found as a field of one (or two) fictive charge(s) inside the sphere.
21. Polarization in Homogeneous Field
Ball's (cylinder's) polarization in a homogeneous electric field: superposition of homogeneously charged (+\(\rho\) and -\(\rho\)) balls (cylinders).
22. Eddy Currents
\(d\) — thickness, \(a\) — size, \(\rho\) — resistivity, \(v\) — velocity.
24. Charge in Magnetic Field
Charge in homogeneous \(\vec{B}\) moves along a cycloid with drift speed \(v = E/B\). Generalized momentum conserved: \(p'_x = mv_x - Byq\), \(p'_y = mv_y + Bxq\). Generalized angular momentum: \(L' = L + \frac{1}{2}Bqr^2\).
25. MHD Generator
\(a\) — length along the direction of \(\vec{E}\), \(v\) — flow velocity, \(B\) — magnetic field, \(b, c\) — other dimensions.
26. Hysteresis
S-shaped curve (loop) in \(B\text{-}H\) coordinates: the loop area gives the thermal energy dissipation density per one cycle.
27. Fields in Matter
\(\vec{P}\) — dielectric polarization vector (volume density of dipole moment). \(\vec{J}\) — magnetization vector (volume density of magnetic moment).
28. Boundary Conditions
At an interface between two substances: tangential \(E\), normal \(D\) (= \(\varepsilon E_t\)), tangential \(H\) (= \(B_t/\mu\)) and normal \(B\) are continuous.
29. Energy Density
Energy stored per unit volume in electromagnetic fields.
31. Current Density
\(n\) — charge carrier density, \(e\) — charge, \(\vec{v}\) — drift velocity, \(\sigma\) — conductivity, \(\rho\) — resistivity.
32. Lenz's Law
The induced current flows in a direction such that it opposes the change in magnetic flux that produced it.
X. Thermodynamics
1. Ideal Gas Law
\(p\) — pressure, \(V\) — volume, \(m\) — mass, \(\mu\) — molar mass, \(R\) — gas constant, \(T\) — temperature.
2. Internal Energy
\(i\) — number of degrees of freedom (3 for monatomic, 5 for diatomic at moderate \(T\)).
3. Molar Volume at Standard Conditions
Volume of one mole of ideal gas at standard conditions (0 C, 1 atm).
4. Adiabatic Processes
Slow compared to the speed of sound, with no heat exchange.
5. Heat Capacity Ratio
\(c_p\) — specific heat at constant pressure, \(c_v\) — at constant volume, \(i\) — degrees of freedom. \(\gamma = c_p/c_v = (i+2)/i\).
6. Boltzmann Distribution
\(\rho_0\) — density at reference level, \(\mu\) — molar mass, \(h\) — height, \(U\) — potential energy, \(k\) — Boltzmann constant.
7. Maxwell Speed Distribution
Gives the fraction of molecules having speed \(v\). \(m\) — molecular mass, \(k\) — Boltzmann constant, \(T\) — temperature.
8. Atmospheric Pressure
\(\rho\) — air density, \(\Delta h\) — height change.
9. Kinetic Theory of Gases
\(n\) — number density, \(m\) — molecular mass, \(\bar{v}\) — RMS speed, \(\nu\) — molecular flux through area \(S\).
10. Carnot Cycle
2 adiabatic + 2 isothermal processes. \(T_1\) — hot reservoir, \(T_2\) — cold reservoir. Can be derived using \(S\text{-}T\) coordinates.
11. Heat Pump (Inverse Carnot)
\(T_1\) — hot side, \(T_2\) — cold side.
12. Entropy
\(S\) — entropy, \(Q\) — heat, \(T\) — temperature (for reversible processes).
13. First Law of Thermodynamics
\(\delta U\) — change in internal energy, \(\delta Q\) — heat added, \(\delta A\) — work done on the system.
14. Second Law of Thermodynamics
Total entropy of an isolated system never decreases. No heat engine can exceed Carnot efficiency.
15. Gas Work
Work done by gas in expansion. For adiabatic processes: \(A = \frac{i}{2}\Delta(pV)\).
16. Dalton's Law
Total pressure of a gas mixture equals the sum of the partial pressures of each component.
17. Boiling
Boiling occurs when the pressure of the saturated vapour equals the external pressure \(p_0\). At the interface between two liquids: \(p_{v1} + p_{v2} = p_0\).
18. Heat Conduction
\(k\) — thermal conductivity, \(S\) — cross-sectional area, \(\Delta T\) — temperature difference, \(l\) — length. Analogy to DC circuits: \(P \leftrightarrow I\), \(\Delta T \leftrightarrow U\), \(k \leftrightarrow 1/\rho\).
19. Heat Capacity
Solids: for low temperatures, \(c \propto T^3\); for high \(T\), \(c = 3Nk\), where \(N\) — number of ions in the crystal lattice (Dulong-Petit law).
20. Surface Tension
\(\sigma\) — surface tension coefficient, \(S\) — surface area, \(l\) — length of boundary, \(R\) — radius of curvature.
21. Stefan-Boltzmann Law
\(\varepsilon\) — emissivity (1 for a perfect black body), \(\sigma\) — Stefan-Boltzmann constant, \(T\) — absolute temperature. For a gray body.
22. Wien's Displacement Law
Relates the peak frequency (or wavelength) of thermal radiation to the temperature of the emitting body.
XI. Quantum Mechanics
1. de Broglie Relations
\(\hbar = h/(2\pi)\) — reduced Planck constant, \(\vec{k}\) — wave vector, \(\omega\) — angular frequency, \(\nu\) — frequency.
3. Uncertainty Principle
For qualitative estimates with non-smooth shapes, \(h\) serves better: \(\Delta p\,\Delta x \approx h\), etc.
4. Spectral Lines
Width of spectral lines is related to the lifetime: \(\Gamma\tau \approx \hbar\).
5. Quantum Harmonic Oscillator
\(\nu_0\) — eigenfrequency. For many eigenfrequencies: \(E = \sum_i h n_i \nu_i\).
6. Tunnelling Effect
A barrier \(\Gamma\) with width \(l\) is easily penetrable if \(\Gamma\tau \approx \hbar\).
7. Bohr's Model
In a classically calculated circular orbit, there is an integer number of wavelengths: \(\lambda = h/(mv)\).
8. Compton Effect
\(\lambda_C\) — Compton wavelength of the electron. If a photon is scattered from an electron, the photon's wavelength increases.
9. Photoelectric Effect
\(A\) — work function. Photocurrent starts at counter-voltage \(U = -(h\nu - A)/e\), saturates for large forward voltages.
XII. Kepler Laws
1. Gravitational Force and Potential
\(G\) — gravitational constant, \(M, m\) — masses, \(r\) — distance between centers.
2. Kepler's I Law
The trajectory of each of two gravitationally interacting point masses is an ellipse, parabola, or hyperbola, with a focus at the center of mass of the system.
3. Kepler's II Law (Equal Areas)
For a point mass in a central force field, the radius vector sweeps equal areas in equal times (conservation of angular momentum).
4. Kepler's III Law
For two point masses in elliptic orbits in an \(r^{-2}\) force field, revolution periods relate as the semi-major axes to the power of \(3/2\).
5. Total Orbital Energy
\(a\) — semi-major axis. Total energy (\(K + \Pi\)) of a body in a gravitational field depends only on the semi-major axis.
6. Nearly Circular Orbits
For small ellipticities \(\varepsilon \ll 1\) trajectories can be considered as having circular shapes with shifted foci.
7. Properties of an Ellipse
\(l_1, l_2\) — distances to the foci, \(\alpha_1 = \alpha_2\) — reflection property (light from one focus is reflected to the other), \(a, b\) — semi-major and semi-minor axes.
9. Runge-Lenz Vector
The Runge-Lenz (ellipticity) vector is a conserved quantity for Kepler orbits, pointing along the semi-major axis toward periapsis.
XIII. Theory of Relativity
1. Lorentz Transformations
\(\gamma = 1/\sqrt{1 - v^2/c^2}\). Rotation of 4D spacetime (Minkowski geometry).
2. Length of 4-Vector (Invariant)
\(s\) — spacetime interval, \(m_0\) — rest mass. These are Lorentz invariants.
3. Relativistic Velocity Addition
\(u, v\) — velocities of two objects, \(w\) — combined velocity. Ensures \(w \le c\).
4. Relativistic Doppler Effect
\(\nu_0\) — emitted frequency, \(v\) — relative velocity (positive for recession).
6. Length Contraction
\(l_0\) — proper length (rest frame), \(l'\) — length measured in the moving frame.
7. Time Dilation
\(t_0\) — proper time (measured in the rest frame of the clock), \(t'\) — time measured by a moving observer.
8. Relativity of Simultaneity
Two events simultaneous in one frame (\(\Delta t = 0\)), are separated in time by \(\Delta t' = -\gamma v\Delta x/c^2\) in a frame moving with velocity \(v\).
9. Relativistic Newton's Law
\(m_0\) — rest mass, \(\vec{p} = m_0\gamma\vec{v}\) — relativistic momentum.
10. Ultrarelativistic Approximation
Valid when the kinetic energy is much greater than the rest energy.
11. Lorentz Transformation for E-B Fields
Parallel components are unchanged; perpendicular components mix under Lorentz boosts.