Statement
5.9.14. Show that the efficiency of a heat engine in a cyclic process is maximal when the entropy of the system does not change.
Solution
In the problem statement, the "system" implies a complete closed thermodynamic system, which includes the working fluid of the heat engine as well as the heat reservoirs (the heater at temperature
Over one complete cycle, the working fluid returns to its initial state. Since entropy
Therefore, the total change in entropy of the closed system over a cycle consists solely of the change in entropy of the heat reservoirs:
Suppose that during a cycle, the engine receives heat
Then the heater loses entropy, and the cooler gains it:
According to the second law of thermodynamics, the entropy of a closed system cannot decrease (
Now let us express the efficiency of the heat engine through the work
Let us substitute the obtained thermodynamic inequality
Conclusion:
The efficiency reaches its maximum possible value
Thus, the efficiency of a heat engine is maximal if the process is completely reversible and the total entropy of the system does not change.