Statement
5.9.4. Find the entropy increment of hydrogen when it expands from volume
Solution
In the general case, the change in entropy of an ideal gas when transitioning from state
where
Let us consider both cases:
b) In an isothermal process
According to the given conditions, the process is isothermal, hence the temperature is constant (
The change in entropy is determined solely by the change in volume from
a) Upon expansion in a vacuum
The expansion of a gas into a vacuum is an adiabatic process with no work done (
Since the internal energy of an ideal gas depends only on its temperature, a constant internal energy implies that the gas temperature remains unchanged (
Thus, the initial and final states of the gas upon expansion in a vacuum are exactly the same as in the isothermal expansion. Since entropy is a state function, its change does not depend on the path the system took to get from the initial state to the final one.
Therefore, the entropy increment in a vacuum will be exactly the same:
Answer
a, b: