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en/5.6.1.md
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| + | ### Statement | ||
| + | |||
| + | $5.6.1.$ [Insert the problem statement] | ||
| + | |||
| + | ### Solution | ||
| + | |||
| + | ### Statement | ||
| + | |||
| + | $5.6.1.$ The average energy of a single gas molecule over a wide temperature range is determined quite accurately by the formula $\bar{\varepsilon} = \frac{i}{2}kT$, where $i$ is the number of degrees of freedom of the molecule, which is equal to the number of coordinates determining its position. Using this formula, find the average energy of $H_2$, $N_2$, $H_2O$, and $CH_4$ molecules at a temperature $T$. | ||
| + | |||
| + | ### Theoretical Background: Degrees of Freedom & Molecular Models | ||
| + | |||
| + | In thermodynamics, a **degree of freedom ($i$)** is an independent coordinate required to completely specify the position and orientation of a molecule in space. It represents the number of independent ways a molecule can move and store kinetic energy. | ||
| + | |||
| + | At normal temperatures, we consider translational motion (the center of mass moving along coordinate axes) and rotational motion (tumbling around axes). Let's visualize all three fundamental models: | ||
| + | |||
| + | **1. Monatomic Gas (e.g., $He$, $Ne$, $Ar$)** | ||
| + | A single atom is treated as a point mass. It can move in 3D space, but its moment of inertia is practically zero, so rotation does not store thermodynamic energy. | ||
| + | |||
| + |  | ||
| + | * **Translational ($i_{\text{trans}}$):** 3 (motion along the $X$, $Y$, and $Z$ axes, as shown by the pink arrows). | ||
| + | * **Rotational ($i_{\text{rot}}$):** 0 | ||
| + | * **Total $i = 3$** | ||
| + | |||
| + | **2. Diatomic Gas (e.g., $H_2$, $N_2$)** | ||
| + | Two atoms connected by a rigid bond (a "dumbbell" model). Its motion is divided into two parts. | ||
| + | |||
| + |  | ||
| + | First, the entire center of mass can move in 3D space. | ||
| + | * **Translational ($i_{\text{trans}}$):** 3 (motion along the $X$, $Y$, and $Z$ axes). | ||
| + | |||
| + |  | ||
| + | Second, it can rotate end-over-end. As shown in the diagram above, if the molecule lies along the $Y$-axis, it can rotate independently around the $X$ and $Z$ axes (indicated by the green arrows). Rotation strictly around its own bond axis ($Y$-axis in this specific orientation) has a negligible moment of inertia and is therefore ignored. | ||
| + | * **Rotational ($i_{\text{rot}}$):** 2 | ||
| + | * **Total $i = 5$** | ||
| + | |||
| + | **3. Polyatomic Non-linear Gas (e.g., $H_2O$, $CH_4$)** | ||
| + | These molecules possess a complex 3D structure with substantial mass distribution around all three spatial axes. | ||
| + | |||
| + |  | ||
| + | * **Translational ($i_{\text{trans}}$):** 3 (motion along $X$, $Y$, and $Z$ axes, always present). | ||
| + | * **Rotational ($i_{\text{rot}}$):** 3 (as shown by the green arrows, the molecule can tumble around the $X$, $Y$, and $Z$ axes independently). | ||
| + | * **Total $i = 6$** | ||
| + | |||
| + | ### Solution | ||
| + | |||
| + | To find the average energy of a single gas molecule using the formula: | ||
| + | $$\bar{\varepsilon} = \frac{i}{2}kT$$ | ||
| + | we determine the number of degrees of freedom $i$ based on the geometric structures analyzed above. | ||
| + | |||
| + | For the diatomic gases $H_2$ and $N_2$, the number of degrees of freedom is $i = 5$. Therefore, the average energy of a single molecule of these gases is: | ||
| + | $$\bar{\varepsilon}_{H_2} = \bar{\varepsilon}_{N_2} = \frac{5}{2}kT$$ | ||
| + | |||
| + | For the non-linear polyatomic molecules $H_2O$ and $CH_4$, the number of degrees of freedom is $i = 6$. Therefore, the average energy of a single molecule is: | ||
| + | $$\bar{\varepsilon}_{H_2O} = \bar{\varepsilon}_{CH_4} = \frac{6}{2}kT = 3kT$$ | ||
| + | |||
| + | #### Answer | ||
| + | $$\bar{\varepsilon}_{H_2} = \bar{\varepsilon}_{N_2} = \frac{5}{2}kT$$ | ||
| + | $$\bar{\varepsilon}_{H_2O} = \bar{\varepsilon}_{CH_4} = 3kT$$ | ||
| + | |||
| + | #### Answer | ||
| + | |||
| + | [Insert a concise answer or boxed result] | ||
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| ### Statement | |||
| $5.6.1.$ [Insert the problem statement] | |||
| ### Solution | |||
| ### Statement | |||
| $5.6.1.$ The average energy of a single gas molecule over a wide temperature range is determined quite accurately by the formula $\bar{\varepsilon} = \frac{i}{2}kT$, where $i$ is the number of degrees of freedom of the molecule, which is equal to the number of coordinates determining its position. Using this formula, find the average energy of $H_2$, $N_2$, $H_2O$, and $CH_4$ molecules at a temperature $T$. | |||
| ### Theoretical Background: Degrees of Freedom & Molecular Models | |||
| In thermodynamics, a **degree of freedom ($i$)** is an independent coordinate required to completely specify the position and orientation of a molecule in space. It represents the number of independent ways a molecule can move and store kinetic energy. | |||
| At normal temperatures, we consider translational motion (the center of mass moving along coordinate axes) and rotational motion (tumbling around axes). Let's visualize all three fundamental models: | |||
| **1. Monatomic Gas (e.g., $He$, $Ne$, $Ar$)** | |||
| A single atom is treated as a point mass. It can move in 3D space, but its moment of inertia is practically zero, so rotation does not store thermodynamic energy. | |||
|  | |||
| * **Translational ($i_{\text{trans}}$):** 3 (motion along the $X$, $Y$, and $Z$ axes, as shown by the pink arrows). | |||
| * **Rotational ($i_{\text{rot}}$):** 0 | |||
| * **Total $i = 3$** | |||
| **2. Diatomic Gas (e.g., $H_2$, $N_2$)** | |||
| Two atoms connected by a rigid bond (a "dumbbell" model). Its motion is divided into two parts. | |||
|  | |||
| First, the entire center of mass can move in 3D space. | |||
| * **Translational ($i_{\text{trans}}$):** 3 (motion along the $X$, $Y$, and $Z$ axes). | |||
|  | |||
| Second, it can rotate end-over-end. As shown in the diagram above, if the molecule lies along the $Y$-axis, it can rotate independently around the $X$ and $Z$ axes (indicated by the green arrows). Rotation strictly around its own bond axis ($Y$-axis in this specific orientation) has a negligible moment of inertia and is therefore ignored. | |||
| * **Rotational ($i_{\text{rot}}$):** 2 | |||
| * **Total $i = 5$** | |||
| **3. Polyatomic Non-linear Gas (e.g., $H_2O$, $CH_4$)** | |||
| These molecules possess a complex 3D structure with substantial mass distribution around all three spatial axes. | |||
|  | |||
| * **Translational ($i_{\text{trans}}$):** 3 (motion along $X$, $Y$, and $Z$ axes, always present). | |||
| * **Rotational ($i_{\text{rot}}$):** 3 (as shown by the green arrows, the molecule can tumble around the $X$, $Y$, and $Z$ axes independently). | |||
| * **Total $i = 6$** | |||
| ### Solution | |||
| To find the average energy of a single gas molecule using the formula: | |||
| $$\bar{\varepsilon} = \frac{i}{2}kT$$ | |||
| we determine the number of degrees of freedom $i$ based on the geometric structures analyzed above. | |||
| For the diatomic gases $H_2$ and $N_2$, the number of degrees of freedom is $i = 5$. Therefore, the average energy of a single molecule of these gases is: | |||
| $$\bar{\varepsilon}_{H_2} = \bar{\varepsilon}_{N_2} = \frac{5}{2}kT$$ | |||
| For the non-linear polyatomic molecules $H_2O$ and $CH_4$, the number of degrees of freedom is $i = 6$. Therefore, the average energy of a single molecule is: | |||
| $$\bar{\varepsilon}_{H_2O} = \bar{\varepsilon}_{CH_4} = \frac{6}{2}kT = 3kT$$ | |||
| #### Answer | |||
| $$\bar{\varepsilon}_{H_2} = \bar{\varepsilon}_{N_2} = \frac{5}{2}kT$$ | |||
| $$\bar{\varepsilon}_{H_2O} = \bar{\varepsilon}_{CH_4} = 3kT$$ | |||
| #### Answer | |||
| [Insert a concise answer or boxed result] | |||